5-Chemistry-Biochemistry-Nucleic Acid-Configuration

double helix

DNA has two linear polynucleotide strands hydrogen-bonded together to form twisted ladder shape {double helix}|.

hydrogen bonds

Nitrogenous bases adenine and thymine in DNA or uracil in RNA can link by two hydrogen bonds, on aromatic-ring side away from pentose and phosphate, if aromatic-ring planes are parallel, with one inverted. Nitrogenous bases cytosine and guanine can link by three hydrogen bonds, on aromatic-ring side away from pentose and phosphate, if aromatic-ring planes are parallel, with one inverted.

ladder

Strands are pentose sugars and phosphodiester bonds and make ladder sides. Strand bonds have opposite direction. Nitrogenous-base and hydrogen-bond-link planar aromatic rings are ladder rungs. Because tetrahedral chemical bonds form at angle, ladder twists and is helical.

base sequence

Ribose sugar (RNA) or deoxyribose sugar (DNA), phosphate group, and nitrogenous-base adenine, guanine, cytosine, and thymine in DNA or uracil in RNA can link to other bases with phosphodiester bonds to make sequences {base sequence} {DNA sequence}.

anti-parallel strands

Two adjacent nucleic-acid polymers {anti-parallel strands} can have opposite bond direction.

base pairing

Hydrogen bonding between adenine and thymine in DNA or uracil in RNA, or between guanine and cytosine {base pairing}, links two DNA strands or DNA and RNA strands.

complementary bases

Hydrogen bonds can form between adenines and thymines in DNA or uracils in RNA, and between cytosines and guanines {complementary bases}.

strand of nucleic acid

polymer chain {strand, DNA}.

supercoiling

Topoisomerase and gyrase affect DNA coiling and can add to or subtract from helix angle {supercoiling}. Circular DNA has negative supercoiling.

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Date Modified: 2022.0225